OsO4, NMO) then NaHSO3 – syn-1,2-Diol cleavage using NaIO4 or HIO4 – Ozonolysis followed by reduction using DMS or Zn/AcOH in Oxidative Cleavage of Alkenes – Permanganate-based Oxidative Cleavage of Alkenes – How do those last three reactions differ in conditions used and products formed? D. Radical Polymerization: – What are the three phases of a radical chain process? (initiation, propagation, termination) – How do we depict electron-pushing in radical-based reaction steps? (fishhook arrows) – In general, radicals positioned at more substituted carbon atoms are more stable than those positioned on less substituted carbons (remember that neutral radical stability often parallels cation stability). – What are monomers?
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